INTERACTIONS BETWEEN NONIONIC SURFACTANT MONOMERS, HYDROPHOBIC ORGANIC-COMPOUNDS AND SOIL

被引:47
作者
EDWARDS, DA
LIU, Z
LUTHY, RG
机构
关键词
SURFACTANT; CMC; SOIL; HYDROPHOBIC ORGANIC COMPOUNDS; SORPTION; BINDING; PARTITION COEFFICIENTS; PAH;
D O I
10.2166/wst.1992.0395
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Nonionic surfactant at aqueous-phase concentrations less than the CMC can affect the distribution of hydrophobic organic compounds (HOCs) in soil/aqueous systems. Sub-CMC levels of nonionic surfactant can enhance the apparent aqueous-phase HOC solubility, increase the soil organic carbon content due to surfactant sorption, and modify the value of the HOC soil/aqueous distribution coefficient. Experimental data quantifying these effects are presented for several HOCs and nonionic surfactants. A method is proposed for predicting the distribution of HOC between soil and bulk solution with sub-CMC aqueous-phase concentrations of nonionic surfactant.
引用
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页码:147 / 158
页数:12
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