ABINITIO DESCRIPTION OF COUTERION SCREENING IN COLLOIDAL SUSPENSIONS

被引：131

作者：

LOWEN, H

MADDEN, PA

HANSEN, JP

机构：

[1] ECOLE NORMALE SUPER LYON,PHYS LAB,F-69364 LYONS 07,FRANCE

[2] UNIV OXFORD,PHYS CHEM LAB,OXFORD OX1 3QZ,ENGLAND

来源：

PHYSICAL REVIEW LETTERS | 1992年 / 68卷 / 07期

关键词：

D O I：

10.1103/PhysRevLett.68.1081

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

A classical version of the Car-Parinello method is proposed. combining density-functional theory for the counterions and molecular dynamics for the macroions, to simulate charged colloidal suspensions. The classic Derjaguin-Landau-Verwey-Overbeek (linear screening) theory is shown to fail for large macroion packing fractions.

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页码：1081 / 1084

页数：4

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