EFFECT OF STIRRING AND TEMPERATURE ON A BELOUSOV-ZHABOTINSKII-LIKE REACTION IN A BATCH REACTOR

被引：26

作者：

DUTT, AK ^{[1
]}

MENZINGER, M ^{[1
]}

机构：

[1] UNIV TORONTO,DEPT CHEM,TORONTO M5S 1A1,ONTARIO,CANADA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1992年 / 96卷 / 21期

关键词：

D O I：

10.1021/j100200a045

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The effect of stirring and temperature on the BZ reaction is using gallic acid (C6H2(OH)3COOH) as the organic substrate in a batch reactor. It is found that increased stirring increases both the induction and oscillation periods. The effect of stirring and temperature on oscillation amplitude does follow a regular order when the probe used is a microelectrode. An unusually large stirring effect on this oscillatory system in the low-temperature region is reported. The results give an indication of the qualitative role of stirring and temperature as bifurcation parameters in a Hopf bifurcation experiment.

引用

页码：8447 / 8449

页数：3

共 36 条

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