ORGANOMETALLIC COMPOUNDS .7. ELECTRON IMPACT FRAGMENTATION OF TRIALKYLTIN HALIDES

被引：48

作者：

GIELEN, M

MAYENCE, G

机构：

[1] Service de Chimie Organique. Faculté, Sciences. Université Libre de Bruxelles

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1968年 / 12卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)93858-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The mass spectra of four different series of trialkyltin halides are described and analysed. The fragmentation rules are found to be identical to those of other alkyltin systems. The fragmentation pattern conforms to hypothesis of preferred SnIV and Sn11 valence state in the tin-containing fragments. The ease of cleavage of a halogen-tin bond in the molecular ion parallels the bond energy in the ground state. © 1968.

引用

页码：363 / &

共 15 条

[1] EVIDENCE FOR A LINEAR RELATION BETWEEN JS']JSN119-CH3 AND DELTAHF OF TRIMETHYLTIN CHLORIDE COMPLEXES [J].