PREPARATION AND PURIFICATION OF ANOMER-FREE METHYL ALPHA-D-[GLUCO-14C(U)] PYRANOSIDE

被引：5

作者：

BARTLETT, GM

SHEPPARD, G

机构：

[1] The Radiochemical Centre, Amersham

来源：

JOURNAL OF LABELLED COMPOUNDS | 1969年 / 5卷 / 03期

关键词：

D O I：

10.1002/jlcr.2590050311

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Methyl α‐D‐[gluco‐14C(U)] pyranoside was synthesized from D‐glucose‐14C(U) and methanol using a cation exchange resin catalyst, but was found to contain 10 % of the β‐anomer as a radiochemical impurity. This was conveniently removed by treatment with a β‐glucosidase — almond emulsin — to yield the pure α‐anomer whose analysis is fully described. Copyright © 1969 John Wiley & Sons, Ltd.

引用

页码：275 / &

共 13 条

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