On the electronic Raman scattering tensor of the trivalent cerium ion in a hexagonal crystal field

被引:7
作者
Koningstein, J. A. [1 ]
Mortensen, O. Sonnich [1 ]
机构
[1] Carleton Univ, EWR Steacie Bldg Chem, Ottawa, ON K1S 5B6, Canada
关键词
D O I
10.1016/0009-2614(68)80123-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A calculation has been made of the scattering matrix for electronic Raman transitions within the F-2(5/2) manifold states of the Ce3+ ion in a crystal field of hexagonal symmetry. Of the two(1)possible transitions one is related to an antisymmetric, the other to a symmetric scattering tensor. The degree of antisymmetry in the former has been found to be extremely dependent on the frequency of the exciting radiation.
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页码:693 / 695
页数:3
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