A NEW METHOD FOR ESTABLISHMENT OF ABSOLUTE-CONFIGURATIONS OF SECONDARY ALCOHOLS BY NMR-SPECTROSCOPY

被引：55

作者：

FUKUSHI, Y

YAJIMA, C

MIZUTANI, J

机构：

[1] Department of Applied Bioscience, Faculty of Agriculture, Hokkaido University, Kita-ku, Sapporo

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 04期

关键词：

D O I：

10.1016/S0040-4039(00)75848-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Axially chiral 2'-methoxy-1,1'-binaphthyl-2- carboxylic acid (MBNC, 2) and 2-(2'-methoxy-1'-naphthyl])3,5-dichlorobenzoic acid (MNCB, 3) were used as chiral derivatizing agents to determine absolute configurations of secondary alcohols by H-1 and C-13 NMR spectroscopy.

引用

页码：599 / 602

页数：4

共 11 条

[1] NUCLEAR MAGNETIC-RESONANCE ENANTIOMER REAGENTS - CONFIGURATIONAL CORRELATIONS VIA NUCLEAR MAGNETIC-RESONANCE CHEMICAL-SHIFTS OF DIASTEREOMERIC MANDELATE, O-METHYLMANDELATE, AND ALPHA-METHOXY-ALPHA-TRIFLUOROMETHYLPHENYLACETATE (MTPA) ESTERS
DALE, JA
MOSHER, HS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (02) : 512 - 519
[2] HASSNER A, 1978, TETRAHEDRON LETT, P4475
[3] FACILE SYNTHESIS OF 1,1'-BINAPHTHYL-2-CARBOXYLATES VIA NUCLEOPHILIC AROMATIC-SUBSTITUTION OF 1-METHOXY-2-NAPHTHOIC ESTERS BY 1-NAPHTHYL GRIGNARD-REAGENTS
HOTTA, H
SUZUKI, T
MIYANO, S
[J]. CHEMISTRY LETTERS, 1990, (01) : 143 - 144
[4] KANGER T, 1992, SYNTHESIS-STUTTGART, P925
[5] OPTICAL RESOLUTION OF 2'-METHOXY-1,1'-BINAPHTHYL-2-CARBOXYLIC ACID, AND APPLICATION TO CHIRAL DERIVATIZING AGENT FOR HPLC SEPARATION OF ENANTIOMERIC ALCOHOLS AND AMINES
MIYANO, S
OKADA, S
HOTTA, H
TAKEDA, M
KABUTO, C
HASHIMOTO, H
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1989, 62 (05) : 1528 - 1533
[6] USE OF AXIALLY CHIRAL 2'-METHOXY-1,1'-BINAPHTHYL-2-CARBOXYLIC ACID AS CHIRAL DERIVATIZING AGENT FOR DISCRIMINATION OF ENANTIOMERIC ALCOHOLS AND AMINES BY (1-H)NMR
MIYANO, S
OKADA, S
HOTTA, H
TAKEDA, MY
SUZUKI, TS
KABUTO, C
YASUHARA, FJ
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1989, 62 (12) : 3886 - 3891
[7] HIGH-FIELD FT NMR APPLICATION OF MOSHER METHOD - THE ABSOLUTE-CONFIGURATIONS OF MARINE TERPENOIDS
OHTANI, I
KUSUMI, T
KASHMAN, Y
KAKISAWA, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (11) : 4092 - 4096
[8] NMR DETERMINATION OF ENANTIOMERIC PURITY
PARKER, D
[J]. CHEMICAL REVIEWS, 1991, 91 (07) : 1441 - 1457
[9] AN EFFICIENT ASYMMETRIC-SYNTHESIS OF ATROPISOMERIC 1,1'-BINAPHTHYLS VIA NUCLEOPHILIC AROMATIC-SUBSTITUTION REACTION
SUZUKI, T
HOTTA, H
HATTORI, T
MIYANO, S
[J]. CHEMISTRY LETTERS, 1990, (05) : 807 - 810
[10] CHEMISTRY OF NOVEL COMPOUNDS WITH MULTIFUNCTIONAL CARBON STRUCTURE .8. APPLICATION OF THE ALPHA-CYANO-ALPHA-FLUOROPHENYLACETIC ACID (CFPA) METHOD TO THE ENANTIOMERIC EXCESS DETERMINATION OF SOME HINDERED ALCOHOLS IN ASYMMETRIC AND NATURAL PRODUCT SYNTHESES
TAKEUCHI, Y
ITOH, N
KAWAHARA, S
KOIZUMI, T
[J]. TETRAHEDRON, 1993, 49 (09) : 1861 - 1870

← 1 2 →