THE CHEMISTRY OF SILYLENOIDS - PREPARATION AND REACTIVITY OF (ALKOXYSILYL)LITHIUM COMPOUNDS

被引：103

作者：

TAMAO, K

KAWACHI, A

机构：

[1] Institut for Chemical Research, Kyoto University, Uji, Kyoto

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 07期

关键词：

SILICON COMPOUNDS; SILYLENOIDS;

D O I：

10.1002/anie.199508181

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ambiphilic reactivity exhibited by the silicon compound 1 contrasts the behavior of neutral silanes and simple silyl anions. This reactivtiy is an indication of silylenoid character, which can be accounted for by the two limiting electronic structures 1 a and 1 b. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

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页码：818 / 820

页数：3

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