MICROWAVE-SPECTRUM OF AMINOBORANE, BH2NH2

被引：70

作者：

SUGIE, M

TAKEO, H

MATSUMURA, C

机构：

[1] National Chemical Laboratory for Industry, Shibuya-ku, Tokyo, 151, Honmachi

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 64卷 / 03期

关键词：

D O I：

10.1016/0009-2614(79)80247-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The unstable species aminoborane, BH2NH2, has been identified as a reaction product of ammonia with diborane by microwave spectroscopy. The rotational constants determined are A = 138212 ± 4 MHz, B = 27487.83 ± 0.10 MHz and C = 22878.44 ± 0.11 MHz for 11BH2NH2 and A = 138199 ± 6 MHz, B = 28420.36 ± 0.11 MHz and C = 23520.78 ± 0.12 MHz for 10BH2NH2. The dipole moment is 1.844 ± 0.015 D. © 1979.

引用

页码：573 / 575

页数：3

共 10 条

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