CONVENIENT PREPARATION AND FUNCTIONALIZATION OF 2-METALATED PENTAFLUOROPROPENES

被引：38

作者：

MORKEN, PA

LU, HY

NAKAMURA, A

BURTON, DJ

机构：

[1] Department of Chemistry, The University of Iowa, Iowa City

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 34期

关键词：

VINYL ORGANOFLUORINE ZINC REAGENT; ORGANOLITHIUM; ZINC; OXIDATIVE COUPLING; HALOGENATION;

D O I：

10.1016/S0040-4039(00)92146-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The title compounds are prepared by metallation of CF3CH = CF2 with LDA or t-BuLi or by metallation of CF3CBr2CF3 with 2 equivalents of zinc. CF3C(ZnX) = CF2 undergoes halogenation, oxidative dimerization, allylation and acylation reactions.

引用

页码：4271 / 4274

页数：4

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