PREPARATION AND REACTIONS OF A NOVEL 5-COORDINATE RUTHENIUM COMPLEX [RUH((R)-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL)2]PF6 AND FORMATION OF THE 1ST CHIRAL MOLECULAR-HYDROGEN COMPLEX [RUH(ETA-2-H2)((R)-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL)2]PF6

被引：39

作者：

TSUKAHARA, T ^{[1
]}

KAWANO, H ^{[1
]}

ISHII, Y ^{[1
]}

TAKAHASHI, T ^{[1
]}

SABURI, M ^{[1
]}

UCHIDA, Y ^{[1
]}

AKUTAGAWA, S ^{[1
]}

机构：

[1] TAKASAGO RES INST INC, OHTA KU, TOKYO 144, JAPAN

来源：

CHEMISTRY LETTERS | 1988年 / 12期

关键词：

D O I：

10.1246/cl.1988.2055

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：2055 / 2058

页数：4

共 15 条

[1] SOLUTION STRUCTURE OF 5-COORDINATE COMPLEXES OF RUTHENIUM(II) - EVIDENCE FOR A SQUARE-PYRAMIDAL GEOMETRY FOR THE CATIONS [RUHPME2PH4]+, [RUC2PHPME2PH4]+ [J].

ASHWORTH, TV ;

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[2] IONIC RUTHENIUM(IV) TRIHYDRIDES AS INTERMEDIATES IN HETEROLYTIC FISSION OF DIHYDROGEN BY 5-CO-ORDINATE HYDRIDORUTHENIUM(II) CATIONS - DIRECT EVIDENCE FOR AN OXIDATIVE ADDITION-REDUCTIVE ELIMINATION PATHWAY [J].

ASHWORTH, TV ;

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[4] H-H, C-H, AND RELATED SIGMA-BONDED GROUPS AS LIGANDS [J].

CRABTREE, RH ;

HAMILTON, DG .

ADVANCES IN ORGANOMETALLIC CHEMISTRY, 1988, 28 :299-338

[5] SYNTHESIS OF NOVEL CHIRAL RUTHENIUM COMPLEXES OF 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL AND THEIR USE AS ASYMMETRIC CATALYSTS [J].

IKARIYA, T ;

ISHII, Y ;

KAWANO, H ;

ARAI, T ;

SABURI, M ;

YOSHIKAWA, S ;

AKUTAGAWA, S .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (13) :922-924

[6] RUTHENIUM(II)-BINAP CATALYZED STEREOSELECTIVE HOMOGENEOUS HYDROGENATION OF 1,3-DIKETONES [J].

KAWANO, H ;

ISHII, Y ;

SABURI, M ;

UCHIDA, Y .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (02) :87-88

[7] MOLECULAR-STRUCTURE OF A CATALYTICALLY ACTIVE CHIRAL RUTHENIUM(II) COMPLEX - CHLOROHYDRIDOBIS[(R)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II) [J].

KAWANO, H ;

ISHII, Y ;

KODAMA, T ;

SABURI, M ;

UCHIDA, Y .

CHEMISTRY LETTERS, 1987, (07) :1311-1314

[8] RUTHENIUM(II)-BINAP COMPLEX CATALYZED ASYMMETRIC HYDROGENATION OF UNSATURATED DICARBOXYLIC-ACIDS [J].

KAWANO, H ;

ISHII, Y ;

IKARIYA, T ;

SABURI, M ;

YOSHIKAWA, S ;

UCHIDA, Y ;

KUMOBAYASHI, H .

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[9] HOMOGENEOUS ASYMMETRIC HYDROGENATION OF FUNCTIONALIZED KETONES [J].

KITAMURA, M ;

OHKUMA, T ;

INOUE, S ;

SAYO, N ;

KUMOBAYASHI, H ;

AKUTAGAWA, S ;

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TAKAYA, H ;

NOYORI, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (02) :629-631

[10] MOLECULAR-HYDROGEN COMPLEXES - COORDINATION OF A SIGMA-BOND TO TRANSITION-METALS [J].

KUBAS, GJ .

ACCOUNTS OF CHEMICAL RESEARCH, 1988, 21 (03) :120-128

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