SYNTHESIS AND CHARACTERIZATION OF A SIMPLE CHIRAL SURFACTANT, SODIUM S-(-)-BETA-CITRONELLYL SULFATE

被引：11

作者：

LEE, CL

OREAR, EA

HARWELL, JH

SHEFFIELD, JA

机构：

[1] UNIV OKLAHOMA,INST APPL SURFACTANT RES,NORMAN,OK 73019

[2] UNIV OKLAHOMA,SCH CHEM ENGN & MAT SCI,NORMAN,OK 73019

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 1990年 / 137卷 / 01期

关键词：

D O I：

10.1016/0021-9797(90)90065-V

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A chiral surfactant, S-(-)-β-citronellyl sulfate, meeting prescribed features has been synthesized from a naturally occurring monoterpenol. Final product yield is 56% after recrystallization. The enantiomer displays a specific rotation in methanol of [α]D = -2.51°, lowers the surface tension of water to 36 dyn/cm, and exhibits a critical micellar concentration of 90 mM. © 1990.

引用

页码：296 / 299

页数：4

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