ENDOHEDRAL AND EXOHEDRAL ADSORPTION IN C-60 - AN ANALYTICAL MODEL

被引：75

作者：

BRETON, J ^{[1
]}

GONZALEZPLATAS, J ^{[1
]}

GIRARDET, C ^{[1
]}

机构：

[1] UNIV FRANCHE COMTE,FAC SCI,PHYS MOLEC LAB,CNRS,URA 772,F-25030 BESANCON,FRANCE

来源：

JOURNAL OF CHEMICAL PHYSICS | 1993年 / 99卷 / 05期

关键词：

D O I：

10.1063/1.466099

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A simple description of the interaction potential between a small molecule and a fullerene 60 cage is discussed on the basis of the continuum approximation. General conditions are obtained for the validity of this continuum approximation and for the confinement mechanism of the molecule inside (or outside) the cage. Application to the insertion of alkali metal ions and rare gas atoms shows that these conditions can adequately interpret the equilibrium positions of inside (outside) adducts, the adsorption energy and the collision experiments between the ions and atoms and the C60 cage.

引用

页码：4036 / 4040

页数：5

共 29 条

[1] RADIAL VIBRATIONS OF A SODIUM-ION INSIDE ICOSAHEDRAL C-60
BALLESTER, JL
DUNLAP, BI
[J]. PHYSICAL REVIEW A, 1992, 45 (11): : 7985 - 7990
[2] BELLONE P, 1990, PHYS REV B, V42, P4201
[3] NONLINEAR VIBRATIONAL DYNAMICS OF A NEON ATOM IN C-60
BUG, ALR
WILSON, A
VOTH, GA
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (20) : 7864 - 7869
[4] CALDWELL KA, 1991, J AM CHEM SOC, V113, P8519, DOI 10.1021/ja00022a048
[5] VIBRATIONAL PROPERTIES OF XE-FULLERENE ADDUCTS - A MOLECULAR-DYNAMICS APPROACH
CARDINI, G
PROCACCI, P
SALVI, PR
SCHETTINO, V
[J]. CHEMICAL PHYSICS LETTERS, 1992, 200 (1-2) : 39 - 45
[6] THE GROUND AND EXCITED-STATES OF C60M AND C60M+ (M=O, F, K, CA, MN, CS, BA, LA, EU, U)
CHANG, AHH
ERMLER, WC
PITZER, RM
[J]. JOURNAL OF CHEMICAL PHYSICS, 1991, 94 (07) : 5004 - 5010
[7] ENDOHEDRAL COMPLEXES - ATOMS AND IONS INSIDE THE C60 CAGE
CIOSLOWSKI, J
FLEISCHMANN, ED
[J]. JOURNAL OF CHEMICAL PHYSICS, 1991, 94 (05) : 3730 - 3734
[8] PHYSISORPTION IN CONFINED GEOMETRY
DERYCKE, I
VIGNERON, JP
LAMBIN, P
LUCAS, AA
DEROUANE, EG
[J]. JOURNAL OF CHEMICAL PHYSICS, 1991, 94 (06) : 4620 - 4627
[9] INTRAMOLECULAR-FORCE-CONSTANT MODEL FOR C-60
FELDMAN, JL
BROUGHTON, JQ
BOYER, LL
REICH, DE
KLUGE, MD
[J]. PHYSICAL REVIEW B, 1992, 46 (19): : 12731 - 12736
[10] INTERACTION POTENTIAL FOR C60 MOLECULES
GIRIFALCO, LA
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (14) : 5370 - 5371

← 1 2 3 →