OXIDATION CATALYSTS PRODUCED BY CATALYTIC-OXIDATION - PREPARATION, REACTIVITY AND X-RAY CRYSTAL-STRUCTURES OF [WO(O-2)(2)(PYO)(2)] AND [MOO(O-2)(2)(PYO)(2)]

被引：33

作者：

GRIFFITH, WP

SLAWIN, AMZ

THOMPSON, KM

WILLIAMS, DJ

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 05期

关键词：

D O I：

10.1039/c39940000569

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The X-ray crystal structures of the pentagonal bipyramidal title complexes are reported (pyO = pyridine-N-oxide); these complexes were made by the oxidation by H2O2 of pyridine, catalysed by [MoO4](2-) and [WO4](2-), and are themselves catalysts for oxidations by H2O2.

引用

页码：569 / 570

页数：2

共 6 条

[1] STUDIES ON TRANSITION-METAL PEROXO COMPLEXES .8. THE NATURE OF PEROXOMOLYBDATES AND PEROXOTUNGSTATES IN AQUEOUS-SOLUTION [J].