SYNTHESIS AND MOLECULAR-STRUCTURE OF TETRARUTHENIUM CLUSTERS CARRYING FACIAL ARENE LIGANDS

被引：10

作者：

BRAGA, D ^{[1
]}

GREPIONI, F ^{[1
]}

PARISINI, E ^{[1
]}

DYSON, PJ ^{[1
]}

INGHAM, SL ^{[1
]}

JOHNSON, BFG ^{[1
]}

BLAKE, AJ ^{[1
]}

机构：

[1] UNIV EDINBURGH,DEPT CHEM,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 05期

关键词：

D O I：

10.1039/c39950000537

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of RU(3)(CO)(12) with 1,3-diisopropenylbenzene (C6H4-{CMeCH(2)}(2)-1,3) and isopropenylbenzene (C6H5-{CMeCH(2)}) in refluxing octane affords the novel species Ru-4(CO)(9)(mu(3)-eta(2):eta(2):eta(2)-C6H4{eta(2)-CMeCH(2)}(2)-1,3) and Ru-4(CO)(10)(mu(3)-mu(2):mu(2):mu(2)-C6H5{eta(2)-CMeCH(2)}) in which the unsaturated systems fully interact with the cluster unit formally supplying 10 and 8 electrons, respectively.

引用

页码：537 / 538

页数：2

共 15 条

[1] ARENE CLUSTERS [J].

BRAGA, D ;

DYSON, PJ ;

GREPIONI, F ;

JOHNSON, BFG .

CHEMICAL REVIEWS, 1994, 94 (06) :1585-1620

[2] STATIC AND DYNAMIC STRUCTURE OF RU3(CO)9(MU-3-ETA-2-ETA-2-ETA-2-C6H6) AT ROOM-TEMPERATURE AND 193-K [J].

BRAGA, D ;

GREPIONI, F ;

JOHNSON, BFG ;

LEWIS, J ;

HOUSECROFT, CE ;

MARTINELLI, M .

ORGANOMETALLICS, 1991, 10 (05) :1260-1268

[3] MOLECULAR-ORGANIZATION AND DYNAMIC BEHAVIOR OF ARENE CLUSTER COMPLEXES IN THE SOLID-STATE - CRYSTAL-STRUCTURES OF [OS4H2(CO)10(ETA-6-C6H5ME)], [OS4H2(CO)10(ETA-6-C6H4ME2)] AND [RU6C(CO)14(ETA-6-C6H3ME3-1,3,5)] [J].

BRAGA, D ;

GREPIONI, F ;

JOHNSON, BFG ;

CHEN, H ;

LEWIS, J .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (10) :2559-2568

[4] CYCLOHEXADIENE AND BENZENE-DERIVATIVES OF [RU5C(CO)15] [J].

BRAGA, D ;

SABATINO, P ;

DYSON, PJ ;

BLAKE, AJ ;

JOHNSON, BFG .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (04) :393-399

[5] REACTION OF [OS4(MU-H)4(CO)12] WITH CYCLOHEXA-1,3-DIENE VIA CHEMICAL ACTIVATION - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF [OS4(MU-H)2(CO)10(ETA-6-C6H6)] AND [OS4(CO)9(ETA-6-C6H6)(ETA-4-C6H8)] AND THEIR INTERCONVERSION [J].

CHEN, H ;

JOHNSON, BFG ;

LEWIS, J ;

BRAGA, D ;

GREPIONI, F ;

PARISINI, E .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (02) :215-219

[6] STEPWISE FORMATION OF THE BIS(BENZENE)HEXARUTHENIUM CARBIDO CARBONYL CLUSTER RU6C(CO)11(ETA-6-C6H6)(MU-3-ETA-2-ETA-2-ETA-2-C6H6) FROM RU6C(CO)17 [J].

DYSON, PJ ;

JOHNSON, BFG ;

LEWIS, J ;

MARTINELLI, M ;

BRAGA, D ;

GREPIONI, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (20) :9062-9068

[7] A FACE-CAPPING BONDING MODE FOR BENZENE IN TRIOSMIUM CARBONYL CLUSTER COMPLEXES [J].

GALLOP, MA ;

GOMEZSAL, MP ;

HOUSECROFT, CE ;

JOHNSON, BFG ;

LEWIS, J ;

OWEN, SM ;

RAITHBY, PR ;

WRIGHT, AH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (07) :2502-2509

[8] BENZENE IN A NEW FACE-CAPPING BONDING MODE - MOLECULAR-STRUCTURES OF [RU6C(CO)11(MU-3-ETA-2-ETA-2-ETA-2-C6H6)(ETA-6-C6H6)] AND [OS3(CO)9(MU-3-ETA-2-ETA-2-ETA-2-C6H6)] [J].

GOMEZSAL, MP ;

JOHNSON, BFG ;

LEWIS, J ;

RAITHBY, PR ;

WRIGHT, AH .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (23) :1682-1684

[9] SEQUENTIAL SYNTHESIS OF SOME TETRAOSMIUM ARENE CLUSTERS [J].

JOHNSON, BFG ;

BLAKE, AJ ;

MARTIN, CM ;

BRAGA, D ;

PARISINI, E ;

CHEN, H .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (14) :2167-2175

[10] A SUBSTITUTED HEXAOSMIUM HYDRIDO CLUSTER WITH BENZENE LIGANDS IN 2 DIFFERENT BONDING MODES - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF [OS6H2(CO)11(ETA-6-C6H6)-(MU-3-ETA-2-ETA-2-ETA-2-C6H6)] [J].

LEWIS, J ;

LI, CK ;

RAITHBY, PR ;

WONG, WT .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (06) :999-1000

← 1 2 →