FRIEDELIN AND RELATED COMPOUNDS .X. PRODUCTS FROM ULTRAVIOLET IRRADIATION OF FRIEDELIN

被引：20

作者：

KOHEN, F

SAMSON, AS

STEVENSON, R

机构：

[1] Department of Chemistry, Brandeis University, Waltham

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 05期

关键词：

D O I：

10.1021/jo01257a034

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ultraviolet irradiation of friedelin (1) in ether solution yields a complex mixture of products from which 5-ethyl-100-vinyldes-A-friedelane (2) and norfriedelane (4) have been separated and identified. In contrast, irradiation of 1 in reagent grade chloroform solution gives, in high yield, ethyl 3,4-secofriedelan-3-oate (7, R = C2H5), characterized by hydrolysis to the corresponding acid (7, R = H) and reduction to the corresponding alcohol (8, R = H). © 1969, American Chemical Society. All rights reserved.

引用

页码：1355 / +

页数：1

共 19 条

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Adams, JR
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Drake, NL
Jacobsen, RP
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[10] Pitts J. N., 1966, CHEM CARBONYL GROUP, P823

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