COMPLEXES OF MOLYBDENUM(V) AND TUNGSTEN(V) . FAR-INFRARED SPECTRA AND SOME OTHER PROPERTIES

被引：34

作者：

RILLEMA, DP

BRUBAKER, CH

机构：

[1] Department of Chemistry, Michigan State University, East Lansing

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 08期

关键词：

D O I：

10.1021/ic50078a014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The far-infrared spectra of tetraalkylammonium complexes of M(OR)Cl5- and M(OR)2X4- and of the dimeric species [W(OR)2Cl3]2 and [W(OR)3Cl2]2 (M = W or Mo; X = Cl or Br; R = CH3, C2H3, or C3H7) were recorded in the range80-650 cm-1. The M-OR stretch has been assigned and several trends which depend on the nature of the alkoxide, halide, and metal are reported. In addition, the preparation and properties of [(C2H5)4N]M(OR)2X4 (M = W or Mo; X = Cl or Br; R = CH3 or C2H6), [(C3H7,)4N]MoOCl4, and [(C4H9)4N]MoOCl4 are given. © 1969, American Chemical Society. All rights reserved.

引用

页码：1645 / &

共 18 条

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