REACTIONS BETWEEN HETEROAROMATIC HALIDES AND LITHIUM DIMETHYLCUPRATE - SYNTHETIC AND MECHANISTIC ASPECTS

被引:8
作者
BABUDRI, F
DINUNNO, L
FLORIO, S
MARCHESE, G
NASO, F
机构
[1] Istituto di Chimica Organica, Facoltà di Scienze, Università di Bari., 70126 Bari
关键词
D O I
10.1016/S0022-328X(00)82543-7
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The reactions of halo-benzothiazoles, -pyridines and -benzofurazans with lithium dimethylcuprate have been investigated. Metal-halogen exchange usually occurs together with cross-coupling. The amount of the product derived from the latter process is increased by adding methyl iodide to the reaction mixtures. The significance of the results is discussed. © 1979.
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页码:265 / 270
页数:6
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