DIAZOCINE CHEMISTRY .6. AN INQUIRY INTO AROMATICITY OF 5,6-DIHYDRODIBENZO[B,F][1,2]DIAZOCINE

被引：38

作者：

PAUDLER, WW

ZEILER, AG

机构：

[1] Department of Chemistry, Clippinger Laboratories, Ohio University, Athens

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 11期

关键词：

D O I：

10.1021/jo01263a004

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of dibenzo[b,f] [1,2]diazocine (1) and its reduction to the 5,6-dihydrodibenzo[b,f] [1,2]diazocine (2) is described. The spectral properties of the latter compound indicate that its central ring, because of the presence of 10 π electrons, is somewhat resonance-stabilized. © 1969, American Chemical Society. All rights reserved.

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页码：3237 / &

相关论文

共 9 条

[1] AROMATIC AND PSEUDOAROMATIC NON-BENZENOID SYSTEMS .3. SYNTHESIS OF SOME TEN PI-ELECTRON SYSTEMS [J].

ALLINGER, NL ;

YOUNGDALE, GA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (06) :1020-&

[2]

[Anonymous], 1910, B SOC CHIM FR II-CH

[3]

GEIGY JR, Patent No. 940165

[4] ELEKTRONENSTRUKTUR UND PHYSIKALISCH-CHEMISCHE EIGENSCHAFTEN VON AZO-VERBINDUNGEN .8. DIE KONJUGATEN SAUREN DES TRANS-AZOBENZOLS UND DES CIS-AZOBENZOLS [J].

GERSON, F ;

HEILBRONNER, E ;

VANVEEN, A ;

WEPSTER, BM .

HELVETICA CHIMICA ACTA, 1960, 43 (07) :1889-1898

[5] THE CYCLOOCTATETRAENYL DIANION [J].

KATZ, TJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (14) :3784-3785

[6] SYM-DIBENZCYCLOOCTATETRAENE ANION RADICAL AND DIANION [J].

KATZ, TJ ;

YOSHIDA, M ;

SIEW, LC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (20) :4516-&

[7] DIAZOCINE CHEMISTRY .V. SYNTHESIS AND REARRANGEMENT OF DIBENZO(B,F)(1,4)DIAZOCINE-6,11(5H,12H)-DIONE [J].

PAUDLER, WW ;

ZEILER, AG .

JOURNAL OF ORGANIC CHEMISTRY, 1969, 34 (07) :2138-&

[8] SYNTHESIS OF DIBENZO[B,F][1,5]DIAZOCINE [J].

PAUDLER, WW ;

ZEILER, AG .

CHEMICAL COMMUNICATIONS, 1967, (21) :1077-&

[9]

VOLPIN ME, 1960, RUSS CHEM REV, V29, P153