CHLOROFLUOROACETYLENE AND BROMOFLUOROACETYLENE BY GAS-PHASE DEHALOGENATION OF 1,1-DIFLUOROETHYLENES

被引:17
作者
RUNGE, A [1 ]
SANDER, WW [1 ]
机构
[1] UNIV HEIDELBERG,INST ORGAN CHEM,NEUENHEIMER FELD 270,W-6900 HEIDELBERG,GERMANY
关键词
D O I
10.1016/S0040-4039(00)97870-5
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Chlorofluoroacetylene and bromofluoroacetylene have been prepared by dehalogenation of dichlorodifluoroathylene and dibromodifluoroetnylene, respectively. The products of the direct dehalogenation with alkali metals as well as of the pyrolysis of trimethylstannyl compounds as "stabilized carbenoids" have been isolated in Ar matrices. © 1990.
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页码:5453 / 5456
页数:4
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