THE GENERAL TREATMENT OF DYNAMIC SOLVENT EFFECTS IN ELECTRON-TRANSFER AT HIGH-TEMPERATURE

被引：17

作者：

WANG, ZY ^{[1
]}

TANG, J ^{[1
]}

NORRIS, JR ^{[1
]}

机构：

[1] ARGONNE NATL LAB,DIV CHEM,ARGONNE,IL 60439

来源：

JOURNAL OF CHEMICAL PHYSICS | 1992年 / 97卷 / 10期

关键词：

D O I：

10.1063/1.463978

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A general treatment of dynamic solvent effects for outer-sphere electron transfer reactions based on the interactions between the electron transfer system and the solvent bath is presented. The electron transfer rate constant as a function of the solvent longitudinal relaxation time is categorized into the three solvent relaxation regions of adiabatic, normal, and fast. New nonadiabatic effects in the very fast solvent relaxation region are identified. A unified picture for adiabatic and nonadiabatic reactions, as well as a criterion for adiabaticity is given.

引用

页码：7251 / 7256

页数：6

共 43 条

[1]

[Anonymous], 1966, ADV ELECTROCH EL ENG

[2] 3-DIMENSIONAL X-RAY CRYSTALLOGRAPHY OF MEMBRANE-PROTEINS - INSIGHTS INTO ELECTRON-TRANSFER [J].