CHEMICAL SYNTHESIS OF P-NITROPHENYL BETA-SOPHOROSIDE AND P-NITROPHENYL BETA-LAMINARABIOSIDE

被引:7
作者
IYER, RN
GOLDSTEIN, IJ
机构
[1] Department of Biological Chemistry, The University of Michigan, Ann Arbor
关键词
D O I
10.1016/S0008-6215(00)80080-4
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Condensation of tetra-O-acetyl-α-d-glucopyranosyl bromide with p-nitrophenyl 4,6-O-benzylidene-β-d-glucopyranoside followed by appropriate deblocking reactions gives rise to an approximately equimolar mixture of p-nitrophenyl β-sophoroside and p-nitrophenyl β-laminarabioside. The two glycosides are readily separated and isolated in pure form by cellulose-column chromatography. © 1969.
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页码:241 / +
页数:1
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