NUCLEAR MAGNETIC-RESONANCE STUDY OF THE SOLVENT EFFECTS ON THIOACETAMIDE

被引：7

作者：

GONZALEZ, G

GRANIFO, J

机构：

[1] Department of Chemistry, Faculty of Science, University of Chile, Santiago

来源：

INORGANICA CHIMICA ACTA | 1979年 / 35卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)93440-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The influence of the solvents nitromethane, acetic anhydride, dioxane, propanediol-1,2-carbonate, ethylacetate, diethylether, tetrahydrofurane, dimethylacetamide, dimethylsulfoxide and hexamethylphosphoric amide on the 1H nmr spectra of the NH protons in free thioacetamide and its pentacarbonylchromium complex has been studied. The chemical shifts for the coordinated thioacetamide show a fair correlation with the solvent donor numbers. The chemical shifts for the free thioacetamide reveal however, the influence of both the donor and acceptor properties of the solvents. Some deviations from the general behaviour are discussed considering possible steric interactions. © 1979.

引用

页码：209 / 213

页数：5

共 37 条

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