SYNTHESIS AND CHARACTERIZATION OF NOVEL SELENIUM-CONTAINING CLUSTERS - CRYSTAL-STRUCTURES OF [RU4(MU-4-SE)2(CO)8(MU-CO)3] AND [RU3(MU-3-SE)2(CO)7(PH2P(CH2)3PPH2)]

被引：36

作者：

JOHNSON, BFG ^{[1
]}

LAYER, TM ^{[1
]}

LEWIS, J ^{[1
]}

MARTIN, A ^{[1
]}

RAITHBY, PR ^{[1
]}

机构：

[1] UNIV CAMBRIDGE, CHEM LAB, LENSFIELD RD, CAMBRIDGE CB2 1EW, ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 429卷 / 03期

关键词：

D O I：

10.1016/0022-328X(92)83193-L

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compound [Ru4(mu-4-Se)2(CO)8(mu-3-CO)3] (1), has been obtained in good yield by vacuum pyrolysis of [Ru3(CO)12] with [Ph2Se2] at 185-degrees-C. Reaction of 1 with 1,3-bis(diphenylphosphino)propane at room temperature affords the novel cluster [Ru3(mu-3-Se)2(CO)7(Ph2P(CH2)3PPh2)] (2). The structures of 1 and 2 have been determined by an X-ray diffraction study.

引用

页码：C41 / C45

页数：5

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