IMPROVED CHARACTERIZATION OF COAL-TAR DISTILLATION CUTS (200-500-DEGREES-C) .2. CAPILLARY GC-MS DETERMINATION OF NEUTRAL AND BASIC NITROGEN AROMATIC-COMPOUNDS AND HYDROXYLATED AROMATIC-COMPOUNDS

被引：20

作者：

LAUER, JC ^{[1
]}

HERNANDEZ, DHV ^{[1
]}

CAGNIANT, D ^{[1
]}

机构：

[1] UNIV METZ,CARBOCHIM & SYNTH ORGAN LAB,F-57045 METZ,FRANCE

来源：

FUEL | 1988年 / 67卷 / 10期

关键词：

Chromatographic Analysis--Gas - Hydrocarbons--Spectroscopic Analysis - Organic Compounds--Chromatographic Analysis - Spectroscopy;

D O I：

10.1016/0016-2361(88)90139-1

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

An analytical procedure for improved characterization of distillation cuts of high and low temperature tars separated into polyaromatic hydrocarbons, basic and neutral nitrogen and hydroxylated polyaromatic compounds (H-PAH), has been described previously. Quantitative determination of the compounds in each class was performed by mass spectrometric analysis and capillary column gas chromatography. As an example the complete analysis of an anthracene oil was made and the results concerning the polyaromatic hydrocarbon fraction described. Analysis of this sample was performed and the results referring to basic and neutral nitrogen and hydroxylated polyaromatic fractions are reported.

引用

页码：1446 / 1455

页数：10

共 29 条

[1] HETEROCOMPOUNDS PRESENT IN ASPHALTENES FROM VARIOUS PRODUCTS OF COAL HYDROGENATION [J].

BODZEK, D ;

KRZYZANOWSKA, T ;

MARZEC, A .

FUEL, 1979, 58 (03) :196-202

[2] SEPARATION AND IDENTIFICATION OF POLYNUCLEAR AROMATIC-COMPOUNDS IN COAL-TAR BY USING GLASS-CAPILLARY CHROMATOGRAPHY INCLUDING COMBINED GAS CHROMATOGRAPHY-MASS SPECTROMETRY [J].

BORWITZKY, H ;

SCHOMBURG, G .

JOURNAL OF CHROMATOGRAPHY, 1979, 170 (01) :99-124

[3]

CALLMER K, 1977, J CHROMATOGR, V136, P45

[4]

CLEON P, 1984, THESIS U METZ FRANCE

[5] LIQUID-CHROMATOGRAPHY OF AZAARENES [J].

COLIN, H ;

SCHMITTER, JM ;

GUIOCHON, G .

ANALYTICAL CHEMISTRY, 1981, 53 (04) :625-631

[6]

DIERICHS A, 1958, PHENOLE BASEN VORKOM

[7] IDENTIFICATION OF CARBAZOLES AND BENZOCARBAZOLES IN A COKER GAS OIL AND INFLUENCE OF CATALYTIC HYDROTREATMENT ON THEIR DISTRIBUTION [J].

DORBON, M ;

IGNATIADIS, I ;

SCHMITTER, JM ;

ARPINO, P ;

GUIOCHON, G ;

TOULHOAT, H ;

HUC, A .

FUEL, 1984, 63 (04) :565-570

[8]

Grant D. W., 1962, GAS CHROMATOGRAPHY, P305

[9] THE COMPOSITION OF THE BASES IN A SUPERCRITICAL GAS EXTRACT [J].

KERSHAW, JR .

FUEL, 1986, 65 (05) :704-706

[10]

LANG KF, 1967, FORTSCHR CHEM FORSCH, V8, P91

← 1 2 3 →