3d electron delocalization from Mossbauer measurements on ferrous halides

被引：26

作者：

Axtmann, R. C. ^{[1
]}

Hazony, Y. ^{[1
]}

Hurley, J. W., Jr. ^{[1
]}

机构：

[1] Princeton Univ, Dept Chem Engn, Princeton, NJ 08540 USA

来源：

CHEMICAL PHYSICS LETTERS | 1968年 / 2卷 / 08期

关键词：

D O I：

10.1016/0009-2614(63)80051-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Measurements on the anhydrous ferrous halides indicate (a) that the Mossbauer quadrupole splitting (QS) and isomer shift (IS) have a common origin and (b) that both properties may provide estimates of 3d electron delocalization. As in the case of similar series of Au. Sn, Sb and Te compounds. the IS in ferrous halides is linearly related to the Pauling electronegativity.

引用

页码：673 / 676

页数：4

共 28 条

[1] ALEKSANDROV AY, 1962, ZH EKSP TEOR FIZ, V43, P1242
[2] AXTMANN RC, 1968, B AM PHYS SOC, V13, P691
[3] MOLECULAR ORBITAL THEORY FOR OCTAHEDRAL AND TETRAHEDRAL METAL COMPLEXES
BASCH, H
VISTE, A
GRAY, HB
[J]. JOURNAL OF CHEMICAL PHYSICS, 1966, 44 (01) : 10 - +
[4] MEASURES OF COVALENCY IN TRANSITION-METAL CHLORIDES
BERSOHN, R
SHULMAN, RG
[J]. JOURNAL OF CHEMICAL PHYSICS, 1966, 45 (06) : 2298 - &
[5] IONIC CHARACTERS FROM MOSSBAUER ISOMER SHIFTS
BHIDE, VG
SHENOY, GK
MULTANI, MS
[J]. SOLID STATE COMMUNICATIONS, 1964, 2 (08) : 221 - 223
[6] CHEMICAL ASPECTS OF MOSSBAUER EFFECT
BRADY, PR
DUNCAN, JF
MOK, KF
[J]. PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1965, 287 (1410) : 343 - +
[7] MOSSBAUER SPECTRUM OF FE2+ IN A SQUARE-PLANAR ENVIRONMENT
CLARK, MG
BANCROFT, GM
STONE, AJ
[J]. JOURNAL OF CHEMICAL PHYSICS, 1967, 47 (10) : 4250 - &
[8] MOSSBAUER STUDIES OF IRON ORGANOMETALLIC COMPLEXES .1. IRON TETRACARBONYL COMPLEXES
COLLINS, RL
PETTIT, R
[J]. JOURNAL OF CHEMICAL PHYSICS, 1963, 39 (12) : 3433 - &
[9] MOSSBAUER SPECTRA OF COMPOUNDS CONTAINING IRON(2) IN STRONG-FIELD TETRAGONAL ENVIRONMENTS
DALE, BW
WILLIAMS, RJP
EDWARDS, PR
JOHNSON, CE
[J]. TRANSACTIONS OF THE FARADAY SOCIETY, 1968, 64 (543P): : 620 - +
[10] ELECTRONIC STRUCTURE OF TRANSITION METAL COMPLEXES WITH NITROSYL LIGAND . MOSSBAUER EFFECT INVESTIGATION
DANON, J
[J]. JOURNAL OF CHEMICAL PHYSICS, 1964, 41 (11) : 3378 - &

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