Deactivation of O-2((1)Delta(g))

被引：56

作者：

Findlay, F. D.

Fortin, C. J.

Snelling, D. R.

机构：

[1] Canadian Armament Research and Development Establishment, Centre de Recherches sur les atomes et les molécules, Que.

来源：

CHEMICAL PHYSICS LETTERS | 1969年 / 3卷 / 04期

关键词：

D O I：

10.1016/0009-2614(69)80026-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Gas phase deactivation of G(2)((1)Delta(g)) has been investigated and rate constants for benzene and oxygen of 5.3 +/- 0.3 x 10(-18) and 2.17 +/- 0.12 x 10(-18) cm(3) molecule(-1) set(-1) respectively, have been measured. Deactivation by nitrogen is much slower and an upper limit of 3 x 10(-21) was obtained.

引用

页码：204 / 206

页数：3

共 9 条

[1] SOME REACTIONS FORMING O2(1SIGMA+/G) IN UPPER ATMOSPHERE [J].

ARNOLD, SJ ;

OGRYZLO, EA .

CANADIAN JOURNAL OF PHYSICS, 1967, 45 (06) :2053-&

[2] ABSOLUTE INTENSITIES OF DISCRETE AND CONTINUOUS ABSORPTION BANDS OF OXYGEN GAS AT 1.26 AND 1.065 MU AND RADIATIVE LIFETIME OF 1LAMDAG STATE OF OXYGEN [J].

BADGER, RM ;

WRIGHT, AC ;

WHITLOCK, RF .

JOURNAL OF CHEMICAL PHYSICS, 1965, 43 (12) :4345-&

[3]

CLARK ID, IN PRESS

[4] ALTITUDE PROFILE OF INFRARED ATMOSPHERIC SYSTEM OF OXYGEN IN DAYGLOW [J].

EVANS, WFJ ;

HUNTEN, DM ;

LLEWELLYN, EJ ;

JONES, AV .

JOURNAL OF GEOPHYSICAL RESEARCH, 1968, 73 (09) :2885-+

[5] 1DELTAG-3SIGMAG- O2 BANDS IN TWILIGHT AND DAY AIRGLOW [J].

GATTINGE.RL ;

JONES, AV .

PLANETARY AND SPACE SCIENCE, 1966, 14 (01) :1-&

[6] 1DELTA-G-3SIGMA-G-O-2 INFRARED EMISSION BAND IN THE TWILIGHT AIRGLOW SPECTRUM [J].

JONES, AV ;

HARRISON, AW .

JOURNAL OF ATMOSPHERIC AND TERRESTRIAL PHYSICS, 1958, 13 (1-2) :45-60

[7] THE SEASONAL VARIATION AND EXCITATION MECHANISM OF THE 1.58 MU-1-DELTA-G-3-SIGMA-G-TWILIGHT AIRGLOW BAND [J].

JONES, AV ;

GATTINGER, RL .

PLANETARY AND SPACE SCIENCE, 1963, 11 (08) :961-974

[8] Production of singlet oxygen in the benzene oxygen photochemical system [J].

Snelling, D. R. .

CHEMICAL PHYSICS LETTERS, 1968, 2 (05) :346-348

[9] SINGLE AND DOUBLE ELECTRONIC TRANSITIONS IN MOLECULAR OXYGEN [J].

WHITLOW, SH ;

FINDLAY, FD .

CANADIAN JOURNAL OF CHEMISTRY, 1967, 45 (18) :2087-&

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