SYNTHESIS AND CHARACTERIZATION OF THE 1ST EXAMPLE OF INSERTION BY PLATINUM(II) INTO A TETRASUBSTITUTED CYCLOPROPANE

被引:12
作者
HOBERG, JO [1 ]
LARSEN, RD [1 ]
JENNINGS, PW [1 ]
机构
[1] MONTANA STATE UNIV,DEPT CHEM,GAINES HALL,BOZEMAN,MT 59717
关键词
D O I
10.1021/om00118a075
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Methodology for the preparation and characterization of insertion of Pt11 into a tetrasubstituted cyclo-propane is established. In this case, the insertion of Pt11 was accomplished with use of 7-methyl-1-methoxy-bicyclo[4.1.0]hept-3-ene. A unique rearrangement involving a platinacyclobutane as an intermediate is suggested. © 1990, American Chemical Society. All rights reserved.
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页码:1334 / 1335
页数:2
相关论文
共 13 条
[1]   TRANSITION-METAL CATALYZED REARRANGEMENTS OF SMALL RING ORGANIC-MOLECULES [J].
BISHOP, KC .
CHEMICAL REVIEWS, 1976, 76 (04) :461-486
[2]   REACTIONS OF PLATINUM COMPLEXES WITH ALKYL-SUBSTITUTED CYCLOPROPANES - FORMATION OF PLATINACYCLOBUTANES [J].
CUSHMAN, BM ;
EARNEST, SE ;
BROWN, DB .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 159 (04) :431-439
[3]  
IRWIN WJ, 1968, TETRAHEDRON LETT, P1937
[4]   A SIMPLE SYNTHESIS OF EXO-TRICYCLO[3.3.1.02,4]NON-6-ENE [J].
JOHNSON, TH ;
CHENG, SS .
SYNTHETIC COMMUNICATIONS, 1980, 10 (05) :381-384
[5]   STEREOSELECTIVITY IN COMPLEXING OF PLATINUM(II) CHLORIDE WITH SUBSTITUTED CYCLOPROPANES [J].
MCQUILLIN, FJ ;
POWELL, KG .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (19) :2123-+
[6]   DIASTEREOSELECTIVE SYNTHESIS OF THE 1ST 2,3,4-TRISUBSTITUTED PLATINA(IV)CYCLOBUTANES [J].
NEILSEN, WD ;
LARSEN, RD ;
JENNINGS, PW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (10) :3307-3308
[7]  
Parshall G.W., 1980, HOMOGENEOUS CATALYSI
[8]   PLATINACYCLOBUTANE CHEMISTRY - CIS-DISUBSTITUTED PLATINACYCLOBUTANE COMPLEX FROM BICYCLO[4.1.0]HEPTANE [J].
PARSONS, EJ ;
JENNINGS, PW .
ORGANOMETALLICS, 1988, 7 (06) :1435-1437
[9]   PLATINACYCLOBUTANE CHEMISTRY - PLATINACYCLOBUTANES FROM BICYCLO [X.1.0] HYDROCARBONS [J].
PARSONS, EJ ;
JENNINGS, PW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (13) :3973-3977
[10]  
POWELL KG, 1971, TETRAHEDRON LETT, V36, P3313