PREPARATION OF EPISULFIDES FROM ALKENES VIA SUCCINIMIDE-N-SULFENYL CHLORIDE OR PHTHALIMIDE-N-SULFENYL CHLORIDE ADDUCTS

被引：57

作者：

BOMBALA, MU ^{[1
]}

LEY, SV ^{[1
]}

机构：

[1] UNIV LONDON IMPERIAL COLL SCI & TECHNOL,DEPT CHEM,LONDON SW7 2AY,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1979年 / 12期

关键词：

D O I：

10.1039/p19790003013

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Succinimide- and phthalimide-sulphenyl chlorides are formed in high yield from the corresponding disulphides by chlorinolysis at 50 °C. These imido-sulphenyl halides react in methylene chloride with cyclohexene, cyclopentene, cyclo-octene, styrene, methylenecyclohexane, and norbornene to form addition products which can subsequently be reduced with lithium aluminium hydride at -78 °C to form episulphides in good yield (49-97%). This new method compares very favourably with other literature routes.

引用

页码：3013 / 3016

页数：4

共 26 条

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