AN EPR STUDY OF THE EFFECT OF SUSPENSION POLYMERIZATION CONDITIONS ON THE PROPERTIES OF GLYCIDYL METHACRYLATE ETHYLENE DIMETHACRYLATE PARTICLES

被引:5
作者
HORAK, D
SMIGOL, V
LABSKY, J
SVEC, F
PILAR, J
机构
[1] Institute of Macromolecular Chemistry, Czechoslovak Academy of Sciences, 162 06 Prague 6
关键词
GLYCIDYL METHACRYLATE ETHYLENE DIMETHACRYLATE COPOLYMER; ELECTRON PARAMAGNETIC RESONANCE; SPIN-LABELED OXIRANE GROUPS; UNIFORM SIZE PARTICLES;
D O I
10.1016/0032-3861(92)90870-3
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Glycidyl methacrylate-ethylene dimethacrylate (GMA-EDMA) copolymer particles were synthesized by both conventional suspension polymerization and a two-step swelling technique. Oxirane groups in the products were modified by reaction with a mixture of 2,2,6,6-tetramethyl-4-aminopiperidine and its 1-oxyl paramagnetic derivative. The characteristics of the synthesized copolymer particles and the modified oxirane groups were studied with respect to the type of synthesis and the type and content of diluent.
引用
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页码:2051 / 2056
页数:6
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