MAGNETIC-PROPERTIES AND CRYSTAL-STRUCTURE OF NOVEL HIGH ANISOTROPIC COMPOUNDS BASED ON THE R-FE-V SYSTEM (R-EQUIVALENT-TO-Y, ND, SM, GD)

被引:63
作者
SHCHERBAKOVA, YV
IVANOVA, GV
YERMOLENKO, AS
BELOZEROV, YV
GAVIKO, VS
机构
[1] Institute of Metal Physics, Ural Division, the USSR Academy of Sciences
关键词
D O I
10.1016/0925-8388(92)90594-Y
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We have investigated the crystal structure and magnetic properties of novel ternary compounds of the composition R2(Fe0.91V0.09)17 (R = Y, Nd, Sm, Gd). X-ray diffraction showed that their crystal structure is a superstructure of a new type based on the CaCu5 structure, but with lattice parameters five times larger than those of CaCu5. The Curie temperature and saturation magnetization of the compounds studied fall into the ranges 440-520 K and 15-30-mu(B) (fu.)-1 at 4.2 K respectively. The influence of dissolved cobalt, carbon and nitrogen on the magnetic properties of the compounds R2(Fe0.91V0.09)17 has been studied.
引用
收藏
页码:199 / 209
页数:11
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