STIMULATED ECHO DESCRIPTION OF COHERENT RAMAN BEAT EPR SPECTROSCOPY

被引：24

作者：

HOFFMANN, E

SCHWEIGER, A

机构：

[1] Laboratorium für Physikalische Chemie, Eidgenössische Technische Hochschule

来源：

CHEMICAL PHYSICS LETTERS | 1994年 / 220卷 / 06期

关键词：

D O I：

10.1016/0009-2614(94)00201-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A theoretical description of the one-pulse and two-pulse coherent Raman beat (CRB) EPR experiment based on the linear regime approximation is presented. It is shown that both experiments are basically superpositions of three-pulse stimulated echo experiments. Analytical expressions for the description of the CRB EPR experiments are given. The predicted features are verified experimentally and by model calculations. In particular, the delay and the blind spot behavior of the two-pulse CRB signal are examined as is the influence of the pulse length on the intensity of the one-pulse CRB signal.

引用

页码：467 / 477

页数：11

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