SYNTHESIS AND PROPERTIES OF VINYL MONOMERS CONTAINING A MESO-TETRAPHENYLPORPHIN RING AND THEIR COPOLYMERS

被引:34
作者
HASEGAWA, E
NEMOTO, JI
KANAYAMA, T
TSUCHIDA, E
机构
[1] Department of Polymer Chemistry, Waseda University, Shinjuku-ku, Tokyo
关键词
D O I
10.1016/0014-3057(78)90076-9
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
To synthesize polymer-covalently bonded meso-tetraphenylporphin derivatives, two porphyrin vinyl monomers, viz., 5-mono(p-acrylamidophenyl)-10,15,20-triphenylporphin and 5,10,15,20-tetra(α,α,α,α-o-methacrylamidophenyl)porphin, were prepared and characterized by elemental analyses, nuclear magnetic resonance, infrared and mass spectrometry. The porphin-bonded polymers were synthesized by radical copolymerization of the porphin monomers with styrene and other monomers and purified by gel permeation chromatography. The spectral properties of these compounds in the Q-band region are also discussed. © 1978.
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页码:123 / 127
页数:5
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