A PHOTOCHEMICALLY-BASED STEREOSELECTIVE ENTRY TO SOME PHENOLIC TRANS 2-ARYLBENZOCYCLOBUTENOL METHYL ETHERS

被引:7
作者
COLL, G
COSTA, A
DEYA, PM
SAA, JM
机构
关键词
D O I
10.1016/0040-4039(91)80871-3
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Photochemical excitation of several 3-hydroxy-2-methoxy-6-methoxymethyl benzophenones 2 efficiently provided the corresponding benzocyclobutenols 3, in a highly stereoselective manner. These compounds on hydrogenolysis and subsequent heating furnished trans-2-arylbenzocyclobutenol methyl ethers 6.
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页码:263 / 266
页数:4
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