C4O2(1,2,3-BUTATRIENE-1,4-DIONE), THE 1ST DIOXIDE OF CARBON WITH AN EVEN NUMBER OF C-ATOMS

被引：39

作者：

MAIER, G

REISENAUER, HP

BALLI, H

BRANDT, W

JANOSCHEK, R

机构：

[1] UNIV BASEL,INST FARBENCHEM,CH-4056 BASEL,SWITZERLAND

[2] GRAZ UNIV,INST THEORET CHEM,A-8010 GRAZ,AUSTRIA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 08期

关键词：

D O I：

10.1002/anie.199009051

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photolysis of the diazaketones 1 or 2 in an argon matrix affords access to butatrienedione 3, which is readily cleaved photochemically into C3O and CO. So far it has not been possible to clarify, either experimentally or computationally, whether 3 has a triplet or a singlet ground state. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：905 / 908

页数：4

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