AMPHIPHILIC AND MESOGENIC CARBOHYDRATES .2. SYNTHESIS AND CHARACTERIZATION OF MONO-O-(NORMAL-ALKYL)-D-GLUCOSE DERIVATIVES

被引：43

作者：

MIETHCHEN, R ^{[1
]}

HOLZ, J ^{[1
]}

PRADE, H ^{[1
]}

LIPTAK, A ^{[1
]}

机构：

[1] LAJOS KOSSUTH UNIV,INST BIOCHEM,H-4010 DEBRECEN,HUNGARY

来源：

TETRAHEDRON | 1992年 / 48卷 / 15期

关键词：

MESOGENICS; AMPHIPHILIC GLUCOSES; MONO-O-(NORMAL-ALKYL)-D-GLUCOPYRANOSES;

D O I：

10.1016/S0040-4020(01)92248-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of various amphiphilic o-(n-alkyl)-D-glucopyranoses, having the long alkyl chain (C8H17 - C16H33) in 2-, 3-, 4- or 6-position are described. The investigations of the thermal behaviour of 6-o-(13a-e), 4-o-(14a-e), 3-o-(15a-e) and 2-o-(n-alkyl)-D-glucopyranoses (16a-e) and the corresponding methyl-alpha-D-glucosides 4a-e, 8a-e and 12a-e, respectively, are summarized in this paper.

引用

页码：3061 / 3068

页数：8

共 30 条

[1] STEREOSELECTIVE REACTION OF METHYL ALPHA-D-GLYCOPYRANOSIDE AND BETA-D-GLYCOPYRANOSIDE WITH ACETIC-ANHYDRIDE IN THE PRESENCE OF TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE [J].

ANGIBEAUD, P ;

UTILLE, JP .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1990, (05) :1490-1492

[2] Use of the benzyl radical in syntheses of methylated sugars Part I 4 6-dimethyl glucose [J].

Bell, DJ ;

Lorber, J .

JOURNAL OF THE CHEMICAL SOCIETY, 1940, :453-455

[3] AMPHIPHILIC CARBOHYDRATE-BASED MESOGENS .3. D-MANNITOL-1-O-NORMAL-ALKYL ETHERS WITH HYDROXY AND 1-O-D-MANNITYL END-GROUPS - NOVEL DOUBLE-HEADED THERMOTROPIC LIQUID-CRYSTALS [J].

DAHLHOFF, WV .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1988, 43 (10) :1367-1369

[4]

DAHLHOFF WV, 1989, Z NATURFORSCH B, V44, P1105

[5]

DAHLHOFF WV, 1990, LIEBIGS ANN CHEM, P811

[6]

DAHLHOFF WV, 1987, Z NATURFORSCH B, V42, P661

[7]

DDAHLHOFF WV, 1987, SYNTHESIS-STUTTGART, P366

[8]

HOLZ J, 1992, THESIS U ROSTOCK

[9] TRIBENZYL-D-GLUCOFURANOSIDES A NEW GROUP OF PHARMACOLOGICALLY ACTIVE COMPOUNDS OF CARBOHYDRATE COMPOSITION .1. ETHERIFIED CARBOHYDRATES [J].

HUBER, G ;

ROSSI, A .

HELVETICA CHIMICA ACTA, 1968, 51 (06) :1185-&

[10] CARBOHYDRATE LIQUID-CRYSTALS [J].

JEFFREY, GA .

ACCOUNTS OF CHEMICAL RESEARCH, 1986, 19 (06) :168-173

← 1 2 3 →