MOLYBDATES OF AROMATIC HETEROCYCLIC-COMPOUNDS - SYNTHESIS AND STRUCTURE OF AN OCTAMOLYBDATE CONTAINING COORDINATELY BOUND PYRAZOLE - [(C3H4N2)2(MO8O26)]4-

被引：35

作者：

GILI, P

MARTINZARZA, P

MARTINREYES, G

ARRIETA, JM

MADARIAGA, G

机构：

[1] UNIV BASQUE COUNTRY, DEPT QUIM INORGAN, BILBAO, SPAIN

[2] UNIV BASQUE COUNTRY, DEPT FIS MAT CONDENSADA, BILBAO, SPAIN

来源：

POLYHEDRON | 1992年 / 11卷 / 01期

关键词：

D O I：

10.1016/S0277-5387(00)83268-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Molybdenum trioxide reacts with pyrazole to give the octamolybdate: (C3H4N2H)4[(C3H4N2)2(Mo8O26)]. The anion [(C3H4N2)2(Mo8O26)]4-, is built of two C3H4N2MoO5 and six MoO6 edge-sharing octahedra. The Mo-NNC3H4 bond length is 2.243(4) angstrom, giving a bond strength of 0.35.

引用

页码：115 / 121

页数：7

共 27 条

[1] SYNTHESIS AND X-RAY STRUCTURE OF A FORMYLATED OCTAMOLYBDATE CLUSTER [(HCO)2(MO8O28)]6- [J].