REDOX BEHAVIOR OF THE OXO-BRIDGED DIRUTHENIUM(III) COMPLEX, [RU-2(MU-O)(MU-MECO(2))(2)(BPY)(2)(MIM)(2)](2+) IN ACETONITRILE IN THE PRESENCE OF VARIOUS PROTON DONORS (BPY=2,2'-BIPYRIDINE, MIM=1-METHYLIMIDAZOLE)

被引：31

作者：

KIKUCHI, A

FUKUMOTO, T

UMAKOSHI, K

SASAKI, Y

ICHIMURA, A

机构：

[1] HOKKAIDO UNIV, GRAD SCH SCI, DIV CHEM, KITA KU, SAPPORO, HOKKAIDO 060, JAPAN

[2] OSAKA CITY UNIV, FAC SCI, DEPT CHEM, SUMIYOSHI KU, OSAKA 558, JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 20期

关键词：

D O I：

10.1039/c39950002125

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Redox potentials of the RU(2)(III,III)-RU(2)(III,II) and RU(2)(III,II)-RU(2)(II,II) processes of [RU(2)(mu-O)(mu-MeCo(2))(2)(bpy)(mim)(2)](2+) in acetonitrile, move to the positive direction remarkably on addition of a strong acid such as toluene-p-sulfonic acid, while two processes are coalesced to show apparent one-step two-electron reduction on addition of weaker proton donors.

引用

页码：2125 / 2126

页数：2

共 39 条

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