INFLUENCE OF LITHIUM CATIONS ON HYDROGEN AND DEUTERIUM ELECTROSORPTION IN PALLADIUM

被引：21

作者：

CZERWINSKI, A

机构：

[1] Department of Chemistry, Warsaw University

来源：

ELECTROCHIMICA ACTA | 1994年 / 39卷 / 03期

关键词：

THIN LAYER PALLADIUM ELECTRODE; HYDROGEN ABSORPTION; DEUTERIUM ABSORPTION; LITHIUM;

D O I：

10.1016/0013-4686(94)80082-0

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A comparative study has been performed of hydrogen and deuterium sorption inside a thin layer palladium electrode from acidic and basic solutions containing lithium cations. Lithium presumed to be incorporated in electrode, has an influence on the alpha- to beta-phase transition only in basic solutions, as a result of more negative potentials values of hydrogen (deuterium) absorption. An isotopic effect has been observed in basic solutions during of absorbed deuterium due to interaction mostly between alpha phase of absorbed hydrogen and incorporated lithium

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页码：431 / 436

页数：6

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