DIASTEREOSELECTIVE AND ENANTIOSELECTIVE CATALYSIS OF THE CARBONYL-ENE REACTION WITH FLUORAL

被引：37

作者：

MIKAMI, K ^{[1
]}

YAJIMA, T ^{[1
]}

TERADA, M ^{[1
]}

KATO, E ^{[1
]}

MARUTA, M ^{[1
]}

机构：

[1] CENT GLASS CO LTD,TOKYO RES CTR,KAWAGOE,SAITAMA 35011,JAPAN

来源：

TETRAHEDRON-ASYMMETRY | 1994年 / 5卷 / 06期

关键词：

D O I：

10.1016/0957-4166(94)80058-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The chiral titanium complex-catalyzed carbonyl-ene reaction with fluoral is shown to serve as an efficient route for the syn-diastereoselective and enantioselective synthesis of CF3-substituted compounds of biological and synthetic importance.

引用

页码：1087 / 1090

页数：4

共 36 条

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