OXIDATIVE 1,2-ARYL REARRANGEMENT IN FLAVANONES USING THALLIUM(III) PARA-TOLYL SULFONATE (TTS) - A NEW USEFUL ROUTE TO ISOFLAVONES

被引:36
作者
SINGH, OV [1 ]
GARG, CP [1 ]
KAPOOR, RP [1 ]
机构
[1] KURUKSHETRA UNIV, DEPT CHEM, KURUKSHETRA 132119, HARYANA, INDIA
关键词
D O I
10.1016/S0040-4039(00)94689-6
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Oxidation of flavanones using thallium(III) p-tolylsulphonate (prepared in situ by the reaction of thallium(III) acetate and p-toluene sulphonic acid) in propionitrile leads to 1,2-aryl shift providing a new useful route to the synthesis of isoflavones. © 1990.
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页码:2747 / 2750
页数:4
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