A REMARKABLE CATALYTIC EFFECT OF CU(II) SPECIES FOR CONJUGATE ADDITION OF GRIGNARD-REAGENTS TO ALPHA,BETA-UNSATURATED ESTERS

被引:35
作者
SAKATA, H [1 ]
AOKI, Y [1 ]
KUWAJIMA, I [1 ]
机构
[1] TOKYO INST TECHNOL,DEPT CHEM,TOKYO 152,JAPAN
关键词
D O I
10.1016/S0040-4039(00)88753-5
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
In the presence of Me3Si-Cl, Cu(II) are not reduced by Grignard reagents but exhibit remarkable catalytic activity for their conjugate addition to α,β-unsaturated esters. © 1990.
引用
收藏
页码:1161 / 1164
页数:4
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