CIRCULAR-DICHROISM OF OLEFINS .4. SEMI-QUANTITATIVE PREDICTION OF THE INTENSITY OF THE COTTON EFFECT OF ALLYL ALCOHOLS AND ETHERS

被引：5

作者：

BERNASSAU, JM

FETIZON, M

HANNA, I

机构：

[1] Ecole Polytechnique, Laboratoire de Synthese Organique

来源：

TETRAHEDRON | 1979年 / 35卷 / 13期

关键词：

D O I：

10.1016/0040-4020(79)80028-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A semi quantitative prediction of the intensity of the Cotton effect of a few allyl alcohols and ethers in the steroid and diterpene series has been derived. It relies on a calculation of the weight of the various conformations and on the allylic bond polarization model. © 1979.

引用

页码：1649 / 1652

页数：4

共 23 条

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[2] OPTICAL-ACTIVITY ASSOCIATED WITH ISOLATED OLEFINIC BONDS .2. EXPERIMENTAL EVIDENCE FOR ROLE OF PI-BOND TORSION IN CIRCULAR-DICHROISM COUPLETS AND QUESTION OF SIGMA(A)-]PI(X)] CONTRIBUTION
ANDERSEN, NH
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[3] OPTICAL-ACTIVITY ASSOCIATED WITH ISOLATED OLEFINIC BONDS .1. ALLYLIC BOND POLARIZATION (ABP) MODEL AND ITS EXTENSION TO HOMOCONJUGATED SYSTEMS
ANDERSEN, NH
COSTIN, CR
SYRDAL, DD
SVEDBERG, DP
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (06) : 2049 - 2051
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[9] GAVRONSKI JK, 1971, TETRAHEDRON LETT, P2493
[10] HUGAND W, 1972, TETRAHEDRON, V28, P1241

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