TRANSITION-METAL COMPLEXES OF L-CYSTEINE CONTAINING DIPEPTIDES AND TRIPEPTIDES

被引:44
作者
CHERIFI, K
DECOCKLEREVEREND, B
VARNAGY, K
KISS, T
SOVAGO, I
LOUCHEUX, C
KOZLOWSKI, H
机构
[1] WROCLAW B BEIRUT UNIV,INST CHEM,14 F JOLIOT CURIE,PL-50383 WROCLAW,POLAND
[2] UNIV LILLE 1,CHIM MACROMOLEC LAB,CNRS UNIT,F-59655 VILLENEUVE DASCQ,FRANCE
[3] LAJOS KOSSUTH UNIV,INST INORGAN & ANALYT CHEM,H-4010 DEBRECEN,HUNGARY
关键词
D O I
10.1016/0162-0134(90)85008-K
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Nickel(II), cobalt(II), zinc(II), and cadmium(II) complexes of Ala-Cys, Phe-Cys, and Ala-Ala-Cys were studied by potentiometric and spectroscopic methods. Ni(II) induces deprotonation and coordination of the amide nitrogens, and the stable monomeric or oligomeric complexes are formed, depending on the metal to ligand molar ratios. Formation of the stable bis-complexes with {S,O} coordination mode is characteristic for cobalt(II), zinc(II), and cadmium(II) ions. © 1990.
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页码:69 / 80
页数:12
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