TETRAMETHYL-ORTHO-QUINODIMETHANE, 1ST MEMBER OF A FAMILY OF CUSTOM-TAILORED CHELETROPIC SPIN TRAPS FOR NITRIC-OXIDE

被引：48

作者：

KORTH, HG

INGOLD, KU

SUSTMANN, R

DEGROOT, H

SIES, H

机构：

[1] NATL RES COUNCIL CANADA,STEACIE INST MOLEC SCI,OTTAWA K1A 0R6,ONTARIO,CANADA

[2] UNIV DUSSELDORF,INST PHYSIOL CHEM 1,W-4000 DUSSELDORF 1,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 07期

关键词：

D O I：

10.1002/anie.199208911

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ortho-quinodimethane 1 reacts quickly and efficiently as a diradical equivalent in a cheletropic reaction with the radical .NO to form 2, which can be very easily observed through ESR spectroscopy. The detection by this technique of the formation of 2 from 1 and .NO released by liver macrophages demonstrates that diradical equivalents of type 1 could be suitable for monitoring .NO production under physiological conditions.

引用

页码：891 / 893

页数：3

共 31 条

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