ON THE REACTION OF (VINYLIMINO)PHOSPHORANES AND RELATED-COMPOUNDS .21. SYNTHESIS AND PROPERTIES OF NOVEL 1,6-METHANOCYCLODECA[B]CYCLOHEPTA[D]PYRROLE

被引：20

作者：

NITTA, M

KAWAJI, H

KANOMATA, N

机构：

[1] Department of Chemistry, School of Science and Engineering, Waseda University, Shinjuku-ku, Tokyo

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 02期

关键词：

D O I：

10.1016/0040-4039(92)88063-B

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The title compound was synthesized by thermal reaction of 3-phosphoranylidene-amino-1,6-methano[10]annulene with 2-chlorotropone in a single step. The examination of H-1 NMR spectrum revealed that there is little contribution of peripheral 18-pi electron conjugation, but it is rather composed of 1-azaazulene and methano[10]annulene moieties.

引用

页码：251 / 254

页数：4

共 24 条

[1] HE-I AND HE-II PHOTOELECTRON-SPECTRA AND CNDO/S AND MNDO MO CALCULATIONS OF SOME BRIDGED [10]ANNULENES [J].