SILOXANES AS TEMPORARY TETHERS IN [2+2] PHOTOCYCLOADDITIONS

被引：24

作者：

CRIMMINS, MT

GUISE, LE

机构：

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 11期

基金：

美国国家科学基金会;

关键词：

2+2] PHOTOCYCLOADDITIONS; TEMPORARY TETHERS; SILOXANES; HOMOENOLATE;

D O I：

10.1016/0040-4039(94)88312-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Intramolecular [2+2] phorocycloadditions utilizing siloxanes as temporary tethers between an enone and olefin results in the products of an intermolecular photocycloaddition with the selectivity of the intramolecular reaction after cleavage of the temporary tether.

引用

页码：1657 / 1660

页数：4

共 26 条

[1] BALDWIN SW, 1979, TETRAHEDRON LETT, P2657
[2] ASYMMETRIC CATALYSIS - PRODUCTION OF CHIRAL DIOLS BY ENANTIOSELECTIVE CATALYTIC INTRAMOLECULAR HYDROSILATION OF OLEFINS
BERGENS, SH
NOHEDA, P
WHELAN, J
BOSNICH, B
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (06) : 2121 - 2128
[3] A NOVEL STRATEGY FOR REGIOCONTROL AND STEREOCONTROL IN [4+2] CYCLOADDITIONS - INTRAMOLECULAR DIELS-ALDER REACTION OF A SILYL ACETAL TRIENE
CRAIG, D
READER, JC
[J]. TETRAHEDRON LETTERS, 1990, 31 (45) : 6585 - 6588
[4] Crimmins M., 1991, COMPREHENSIVE ORGANI, V5, P123
[5] Crimmins M. T., 1993, ORG REACTIONS, V44, P297
[6] INTRAMOLECULAR PHOTOCYCLOADDITION CYCLOBUTANE FRAGMENTATION - A HIGHLY STEREOSELECTIVE TOTAL SYNTHESIS OF (+/-)-PENTALENIC ACID
CRIMMINS, MT
DELOACH, JA
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1984, 49 (11) : 2076 - 2077
[7] ADDITION OF ZINC HOMOENOLATES TO ACETYLENIC ESTERS AND AMIDES - A FORMAL [3+2] CYCLOADDITION
CRIMMINS, MT
NANTERMET, PG
TROTTER, BW
VALLIN, IM
WATSON, PS
MCKERLIE, LA
REINHOLD, TL
CHEUNG, AWH
STETSON, KA
DEDOPOULOU, D
GRAY, JL
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (05) : 1038 - 1047
[8] INTRAMOLECULAR ENONE-FURAN PHOTOCYCLOADDITIONS - STUDIES TOWARD THE SYNTHESIS OF GINKGOLIDE-A AND GINKGOLIDE-B
CRIMMINS, MT
THOMAS, JB
[J]. TETRAHEDRON LETTERS, 1989, 30 (44) : 5997 - 6000
[9] ADDITION OF ZINC HOMOENOLATES TO ACETYLENIC ESTERS - A FORMAL [3 + 2] CYCLOADDITION
CRIMMINS, MT
NANTERMET, PG
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (14) : 4235 - 4237
[10] INTRAMOLECULAR PHOTOCYCLOADDITIONS CYCLOBUTANE FRAGMENTATION - TOTAL SYNTHESIS OF (+/-)-PENTALENENE, (+/-)-PENTALENIC ACID, AND (+/-)-DEOXYPENTALENIC ACID
CRIMMINS, MT
DELOACH, JA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (04) : 800 - 806

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