Evidence for long-lived ion-molecule collision complexes from numerical studies

被引：37

作者：

Dugan, J. V., Jr. ^{[1
]}

Rice, J. H.

Magee, J. L.

机构：

[1] NASA, Lewis Res Ctr, Cleveland, OH 44135 USA

[2] Univ Notre Dame, Notre Dame, IN 46556 USA

来源：

CHEMICAL PHYSICS LETTERS | 1969年 / 3卷 / 05期

关键词：

D O I：

10.1016/0009-2614(69)80243-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Collision lifetimes T-c have been calculated numerically for ion-molecule collisons. Dipoles cause multiple reflections leading to T-c values much ionger than specular reflection periods. Langevin collisions yield simple specular reflections. The interaction has been studied via a computer-plotter system.

引用

页码：323 / 326

页数：4

共 10 条

[1] Calculation of interchange reaction rates from transition times [J].