VERY HIGH DIASTEREOFACIAL SELECTIVITY IN THE NUCLEOPHILIC EPOXIDATION OF N-(PARA-TOLYLSULPHONYL)VINYLSULPHOXIMINES

被引：17

作者：

BAILEY, PL

CLEGG, W

JACKSON, RFW

METHCOHN, O

机构：

[1] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,BEDSON BLDG,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

[2] STERLING ORGAN,NEWCASTLE TYNE NE3 3TT,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1990年 / 01期

关键词：

D O I：

10.1039/p19900000200

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Nucleophilic epoxidation of N-(p-tolylsulphonyl)vinylsulphoximines (6) using lithium t-butyl hydroperoxide proceeds with very high diastereofacial selectivity, the sense of which was established by a single crystal X-ray structure determination, to give N-(p-tolylsulphonyl)phenylsulphoximino-oxiranes (5) in good yield.

引用

页码：200 / 202

页数：3

共 16 条

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