DEPHOSPHORYLATION OF CYANO DIETHYL PHOSPHATES BY REDUCTION WITH LITHIUM LIQUID-AMMONIA - AN EFFICIENT METHOD FOR CONVERSION OF CARBONYL-COMPOUNDS INTO NITRILES

被引：14

作者：

YONEDA, R ^{[1
]}

OSAKI, T ^{[1
]}

HARUSAWA, S ^{[1
]}

KURIHARA, T ^{[1
]}

机构：

[1] OSAKA UNIV PHARMACEUT SCI,2-10-65 KAWAI,OSAKA 580,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1990年 / 03期

关键词：

D O I：

10.1039/p19900000607

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cyano diethyl phosphate derivatives of aromatic carbonyl compounds and α,β-unsaturated ketones were successively dephosphorylated by reduction with lithium in liquid ammonia followed by treatment with isoprene or alkyl halides to give β,γ-unsaturated nitrites or α-alkyl-βγ-unsaturated nitriles in moderate to good yields.

引用

页码：607 / 610

页数：4

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